Synthesis and magnetic study of new mu-oxalato dinuclear copper (II) complexes

Authors
Mukherjee, PS Maji, TK Koner, S Rosair, G Chaudhuri, NR
Citation
Ps. Mukherjee et al., Synthesis and magnetic study of new mu-oxalato dinuclear copper (II) complexes, I J CHEM A, 40(5), 2001, pp. 451-455
Citations number
14
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
40
Issue
5
Year of publication
2001
Pages
451 - 455
Database
ISI
SICI code
0376-4710(200105)40:5<451:SAMSON>2.0.ZU;2-S
Abstract
Three new mu -oxalato dinuclear copper(II) complexes [L(H2O)CuOxCu(H2O)L](C lO4)(2) [L = 4-(2-aminoethyl)morpholine (aem), (1), 1-(2-aminoethyl)piperid ine (ampp), (2) and 1-(2-aminoethyl)pyrrolidine (ampy), (3)1] have been syn thesized and characterized by X-ray single crystal analysis (1), IR, therma l analysis and magnetic measurements. Low temperature magnetic measurements of these complexes show the existence of strong antiferromagnetic interact ion between the copper(II) ions.