The effects of preozonation on interactions among coagulants, particles, an
d natural organic matter were examined at bench scale through a series of j
ar tests using different organic matter, pH values, and coagulants. When al
um was used as a coagulant, preozonation hindered turbidity and dissolved o
rganic matter (DOM) removal at the conditions tested. When cationic polymer
s were used as the coagulant, however, preozonation led to small but statis
tically significant increases in the removal of both turbidity and DOM. Whe
n polyaluminum chloride was used as the coagulant for several natural water
s, preozonation aided turbidity and DOM removal in one instance and hindere
d removal of particles and organic materials in another instance. The autho
rs hypothesize that preozonation reduces the surface charge of particulates
, leading to better coagulation by charge neutralization.