Kk. Patankar et al., Electrical conduction and magnetoelectric effect in CuFe1.8Cr0.2O4-Ba0.8Pb0.2TiO3 composites, J ELECTROCE, 6(2), 2001, pp. 115-122
Magnetoelectric composites of CuFe1.8Cr0.2O4-Ba0.8Pb0.2TiO3 were prepared u
sing high temperature solid-state reaction technique. X-ray structural anal
ysis of these composites confirms the presence of both the phases in the co
mposite. Detailed studies of dielectric properties (epsilon', tan delta and
sigma (ac)) as a function of frequency (100 Hz to 1 MHz) and temperature (
30 degreesC to 250 degreesC) show that these compounds exhibit diffuse ferr
oelectric phase transitions. Results of ac conductivity, dc resistivity and
thermoelectric power measurements show that conduction occurs by hopping o
f charge carriers. The magnetoelectric effect has been studied as a functio
n of intensity of magnetic field. The electrical polarisation was induced i
n piezoelectric (Ba0.8Pb0.2TiO3) phase as result of strain induced in the f
errite (CuFe1.8Cr0.2O4) phase by the applied magnetic field. The Jahn-Telle
r distortion caused in the ferrite lattice by Jahn-Teller ions like Cu2+ an
d Cr3+ is also responsible for the elastic coupling of strain to the Ba0.8P
b0.2TiO3 phase.