Vibrational spectra study of Mo(V) phosphates as examples of different geometries of dimolybdenyl species

Authors
Daturi, M Busca, G Guesdon, A Borel, MM
Citation
M. Daturi et al., Vibrational spectra study of Mo(V) phosphates as examples of different geometries of dimolybdenyl species, J MAT CHEM, 11(6), 2001, pp. 1726-1731
Citations number
29
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS CHEMISTRY
ISSN journal
09599428 → ACNP
Volume
11
Issue
6
Year of publication
2001
Pages
1726 - 1731
Database
ISI
SICI code
0959-9428(2001)11:6<1726:VSSOMP>2.0.ZU;2-R
Abstract
Three different phosphate structures, alpha -K2Mo2P2O11, beta -K2Mo2P2O11 a nd CdMoPO6, in which molybdenum(V) octahedra are assembled in different way s, have been studied by vibrational spectroscopy techniques. A correlation is given between crystal structure and infrared and Raman band behaviour wh ich allows identification of vibrational modes sensitive to a particular co nfiguration of molybdenum species. This represents a powerful tool for stru cture characterisation when amorphous or single layer supported phases are under study.