Qq. Zhang et al., A comparison of the reactions of pentacarbonyliron with cyclic thioethers and related dialkyl sulfides, J ORGMET CH, 627(2), 2001, pp. 201-205
A facile synthesis of the compounds Fe(CO)(4)(ER2), where ER2 = SMe2, SEt2,
or SeMe2, has been developed. It involves treatment of Fe(CO)(5) with trim
ethylamine N-oxide and the Group 16 compound. With cyclic thioethers, the s
ame synthetic procedure yields dinuclear bis-thiolato complexes of the type
Fe-2(CO)(6){mu -SCH2CH(R)S}, where R = H or Me. The structure of Fe-2(CO)(
6){mu -SCH2CH(Me)S} has been determined from X-ray diffraction data. (C) 20
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