The ceramics of PbTiO3 and its powders have been prepared by a soi-gel proc
ess. The constitution of its phase and structure was examined by x-ray diff
raction and Fourier transform infrared spectroscopy. Characterization studi
es were performed to determine the effects of particle size and degree of t
etragonality. The dielectric properties of ceramics and powders of PbTiO3,
composited with paraffin, were measured from 1 MHz to 18 GHz. All samples e
xhibited evidence of relaxation phenomena in their dielectric spectra. The
relaxation frequencies increased with decreasing particle size.