EGS4 Monte Carlo simulations have been performed to examine general ca
vity theory for a number of TLD cavity materials irradiated in megavol
tage photon and electron beams. The TLD materials were LiF, Li2B4O7, C
aF2 and CaSO4 irradiated in Perspex, water, Al, Cu and Pb phantoms. Fo
r megavoltage photon beams, this has been done by determining the dose
component (1 - d) resulting from photon interactions in the cavity co
mpared with the dose component resulting from photon interactions in t
he phantom material (df by Monte Carlo simulations and analytical tech
niques. The results indicate that the Burlin exponential attenuation t
echnique can overestimate the dose contribution from photon interactio
ns in a I mm thick LiF cavity by up to 100% compared with the Monte Ca
rlo results for LF TLDs irradiated in a water or Perspex phantom. Howe
ver, there is agreement to within 1% in the quality dependence factor,
determined from Burlin's cavity theory, Monte Carlo simulations and e
xperimental measurements for LiF and Li2B4O7 TLDs irradiated in a Pers
pex or a water phantom. The agreement was within 3% for CaF2 TLDs. How
ever there was disagreement between Monte Carlo simulations and Burlin
's theory of 6 and 12% for LiF TLDs irradiated in copper and lead phan
toms respectively. The adaptation of Burlin's photon cavity theory and
other modifications to his photon general cavity theory for electrons
have been shown to be seriously flawed.