The heavy elements formed by neutron capture processes have an interesting
history from which we can extract useful clues to and constraints upon the
star formation and nucleosynthesis history of Galactic matter. Of particula
r interest are the heavy element compositions of extremely metal-deficient
stars. At metallicities [Fe/H] less than or equal to -2.5, stellar abundanc
e data (for both halo field stars and globular cluster stars) provides stro
ng confirmation of the occurrence of a robust r-process mechanism for the p
roduction of the main r-process component, at mass numbers A greater than o
r similar to 130-140. The identification of an environment provided by mass
ive stars and associated Type II supernovae as an r-process site seems comp
elling. Scatter in the ratio [r-process/Fe] provides a measure of the level
of inhomogeneity characteristic of the halo gas at that early epoch. Incre
asing levels of s-process enrichment with increasing metallicity reflect th
e delayed contributions from the intermediate mass stars that provide the s
ite for s-process nucleosynthesis during the AGE phase of their evolution.
For the mass region A less than or similar to 130, the abundance patterns i
n even the most metal deficient stars are not consistent with the solar sys
tem r-process abundance distribution, providing evidence for the fact that
the r-process isotopes identified in solar system matter are in fact the pr
oducts of two distinct r-processes nucleosynthesis events. We review recent
observational studies of heavy element abundances in low metallicity stars
and explore some implications of these results for nucleosynthesis and ear
ly Galactic chemical evolution.