Magnetism of Nd3+ ions in Nd5Rh4Sn10 - art. no. 184402

In the family of rare-earth transition metal silicides, compounds belonging to the series R5Ir4Si10 (where R is a rare-earth element from Dy to Lu and Y) exhibits multiple phase transitions. However, there exists a series R5R h4Sn10, which can only be formed with light rare-earth elements from Ce to Nd. In this work, we report detailed resistivity, susceptibility, magnetiza tion, heat-capacity, thermal expansion,and magnetoresistance studies, which suggest that the Nd3+ moments undergo unusual magnetic orderings in a sing le crystal of Nd5Rh4Sn10. A second-order magnetic transition at 7.15 K is f ollowed by a first-order transition below 6.15 K that results in a huge hea t-capacity peak of 100 J/mol K. The two transitions are strongly suppressed by a magnetic field (4 T) along the c axis while they are Only weakly infl uenced by fields as high as 16 T in the basal plane. Moreover, the magnetor esistance data along the a and c axes from 1.5 to 15 K in fields up to 18 T revealed a giant positive magnetoresistance along the a axis below 6 K and clear evidence of a metamagnetic transition along the c axis. We attribute this unusual magnetic behavior to the unique crystal structure of this Nd5 Rh4Sn10 compound with its three different Nd sites.