Mathematical models of phase transitions in solids lead to the variational
problem, minimize f(Omega)W(Du) dx, where W has a multi-well structure, i.e
. W = 0 on a multi-well set K and W > 0 otherwise. We study this problem in
two dimensions in the case of equal determinant, i.e, for K = SO(2)U-1 boo
lean OR...boolean OR SO(2)U-k or K = O(2)U-1 boolean OR...boolean OR O(2)U-
k for U-1,...,U-k is an element of M-2x2 with det U-i = delta, in three dim
ensions when the matrices U, are essentially two-dimensional and also for K
= SO(3)(U) over cap (1) boolean OR...boolean OR SO(3)(A) over cap (k) for
U-1,...,U-k is an element of M-3X3 with (adj (UiUi)-U-T)(33) = delta (2), w
hich arises in the study of thin films. Here, (U) over cap (i) denotes the
(3 x 2) matrix formed with the first two columns of U-i. We characterize ge
neralized convex hulls, including the quasiconvex hull, of these sets, prov
e existence oi minimizers and identify conditions for the uniqueness of the
minimizing Young measure. Finally, we use the characterization of the quas
iconvex hull to propose 'approximate relaxed energies', quasiconvex functio
ns which vanish on the quasiconvex hull of K and grow quadratically away fr
om it.