Polarization diagram of the electrochemical impedance of second order: A theory that accounts for the diffusion of reactants

Authors
Elkin, VV Mishuk, VY Alekseev, VN Grafov, BM
Citation
Vv. Elkin et al., Polarization diagram of the electrochemical impedance of second order: A theory that accounts for the diffusion of reactants, RUSS J ELEC, 37(4), 2001, pp. 399-408
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
37
Issue
4
Year of publication
2001
Pages
399 - 408
Database
ISI
SICI code
1023-1935(200104)37:4<399:PDOTEI>2.0.ZU;2-4
Abstract
With the aim of improving diagnostic possibilities of second-order impedanc e spectroscopy, a theory is put forward for a polarization diagram of a sec ond-order impedance for reactions with charge transfer. The theory takes in to account the diffusion of discharging particles in the absence of their s pecific adsorption.