Catalytic activity of palladium chelates in the direct synthesis of hydrogen peroxide

Authors
Ippolitov, EG Artemov, AV Pokhabova, IV Tripol'skaya, TA
Citation
Eg. Ippolitov et al., Catalytic activity of palladium chelates in the direct synthesis of hydrogen peroxide, RUSS J IN C, 46(5), 2001, pp. 642-645
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
5
Year of publication
2001
Pages
642 - 645
Database
ISI
SICI code
0036-0236(200105)46:5<642:CAOPCI>2.0.ZU;2-G
Abstract
The catalytic effect of various palladium chelates on the liquid-phase oxid ation of 1,2,3,4-tetrahydronaphthalene (THN) and of hydrogen with oxygen wa s studied. Homogeneous catalysts are more active in THN oxidation than supp orted catalysts. Of the homogeneous catalysts, cis-[1,2-(TsN)(N)C6H4](2)Pd is the most active.