Reaction of 2-isobutoxy-4,4,6-trimethyl-1,3,2-dioxaborinane with dinitriles

Authors
Kuznetsov, VV Brusilovskii, YE Mazepa, AV
Citation
Vv. Kuznetsov et al., Reaction of 2-isobutoxy-4,4,6-trimethyl-1,3,2-dioxaborinane with dinitriles, RUSS J ORG, 36(12), 2000, pp. 1809-1811
Citations number
7
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
36
Issue
12
Year of publication
2000
Pages
1809 - 1811
Database
ISI
SICI code
1070-4280(200012)36:12<1809:RO2WD>2.0.ZU;2-9
Abstract
2-Isobutoxy-4,4,6-trimethyl-1,3,2-dioxaborinane reacts with bis(2-cyanoethy l) ether and bis[2-(2-cyanoethoxy)ethyl] ether to afford the corresponding bis(5,6-dihydro-4,4,6-trimethyl-1,3-4H-oxazin-2-y1) derivatives which are r eadily hydrolyzed in aqueous alkali, yielding 4-amino-4-methyl-2-pentanol.