Regioselectivity in coupling of allyl halides with copper acetylene complexes

Authors
Matveeva, ED Yerin, AS Kurts, AL
Citation
Ed. Matveeva et al., Regioselectivity in coupling of allyl halides with copper acetylene complexes, RUSS J ORG, 36(11), 2000, pp. 1572-1576
Citations number
4
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
36
Issue
11
Year of publication
2000
Pages
1572 - 1576
Database
ISI
SICI code
1070-4280(200011)36:11<1572:RICOAH>2.0.ZU;2-V
Abstract
A regiselectivity of 1,4-enynes formation in reaction of a-acetylene copper complexes (copper acetylenides, alkynyliodocuprates, dialkynylcuprates) wi th various allyl halides was investigated. The most selective reaction was observed between dialkynylcuprates and geranyl bromide.