Synthetic transformations of higher terpenoids: V. 2-methyl-4,5-dioxo-3-ethoxycarbonyl-4,5-dihydroindole, a new dienophile. Synthesis of indoloterpenes from levopimaric acid

Authors
Chernov, SV Shults, EE Shakirov, MM Gatilov, YV Bagryanskaya, IY Tolstikov, GA
Citation
Sv. Chernov et al., Synthetic transformations of higher terpenoids: V. 2-methyl-4,5-dioxo-3-ethoxycarbonyl-4,5-dihydroindole, a new dienophile. Synthesis of indoloterpenes from levopimaric acid, RUSS J ORG, 36(11), 2000, pp. 1623-1633
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
36
Issue
11
Year of publication
2000
Pages
1623 - 1633
Database
ISI
SICI code
1070-4280(200011)36:11<1623:STOHTV>2.0.ZU;2-W
Abstract
2-Methyl-4,5-dioxo-3-ethoxycarbonyl-4,5-dihydroindol is an active dienophil e that via [4+2]-cycloaddition to the levopimaric acid and to the cyclopent adiene affords indole alkaloids of new structural types.