Measurement of the solubilities of undecanolide and pentadecanolactone in supercritical carbon dioxide by supercritical fluid chromatography

Authors
Mishima, K Matsuyama, K Baba, M Ohuchi, M Hakushi, T
Citation
K. Mishima et al., Measurement of the solubilities of undecanolide and pentadecanolactone in supercritical carbon dioxide by supercritical fluid chromatography, SOL EX R D, 8, 2001, pp. 215-222
Citations number
15
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT-JAPAN
ISSN journal
13417215 → ACNP
Volume
8
Year of publication
2001
Pages
215 - 222
Database
ISI
SICI code
1341-7215(2001)8:<215:MOTSOU>2.0.ZU;2-P
Abstract
The solubilities of undecanolide (UDL) and pentadecanolactone (PDL) in supe rcritical carbon dioxide (SC-CO2) were measured at 308.2 K and 318.2 K over a pressure range from 12.2 to 25.3 MPa by the degree of retention in super critical fluid chromatography. The results were compared with the data for UDL and PDL obtained by flow type solubility measurements. To obtain the so lubility data from the degree of retention, a cell constant, C was determin ed from the solubility data of solutes measured by the flow type apparatus. Measured solubility data were correlated by a solution model based on the regular solution concept.