Tandem glycol cleavage-intramolecular [4+2] cycloadditions mediated by Dess-Martin periodinane

Authors
Lena, JIC Hernando, JIM Ferreira, MDR Altinel, E Arseniyadis, S
Citation
Jic. Lena et al., Tandem glycol cleavage-intramolecular [4+2] cycloadditions mediated by Dess-Martin periodinane, SYNLETT, (5), 2001, pp. 597-600
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
5
Year of publication
2001
Pages
597 - 600
Database
ISI
SICI code
0936-5214(200105):5<597:TGC[CM>2.0.ZU;2-L
Abstract
The product distribution on oxidation of vicinal unsaturated diols using De ss-Martin periodinane (DMP) under various conditions is investigated. The p rocess depends upon 1,2-diol-stereochemistry and constitutes a useful metho d for glycol fission offering molecular complexity.