Electron spin resonance (ESR) studies under hydrostatic pressure were perfo
rmed to investigate the electronic structure of orthorhombic linear polymer
phase A(1)C(60) (A=Rb, Cs). Pressure dependence of the antiferromagnetic t
ransition temperature and the Curie-Weiss temperature was investigated by t
he ESR intensity. On the basis of these data, together with the electrical
resistivity on a single crystal under pressure (Phys. Rev. B56, 6627 (1997)
), a Mott-Hubbard phase diagram is proposed for Rb1C60. At ambient pressure
this material is suggested to be on the border of the metal-insulator tran
sition.