ESR under pressure on polymer phase A(1)C(60) (A=Rb, Cs)

Citation
H. Sakamoto et al., ESR under pressure on polymer phase A(1)C(60) (A=Rb, Cs), SYNTH METAL, 121(1-3), 2001, pp. 1103-1104
Citations number
11
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
121
Issue
1-3
Year of publication
2001
Pages
1103 - 1104
Database
ISI
SICI code
0379-6779(20010315)121:1-3<1103:EUPOPP>2.0.ZU;2-D
Abstract
Electron spin resonance (ESR) studies under hydrostatic pressure were perfo rmed to investigate the electronic structure of orthorhombic linear polymer phase A(1)C(60) (A=Rb, Cs). Pressure dependence of the antiferromagnetic t ransition temperature and the Curie-Weiss temperature was investigated by t he ESR intensity. On the basis of these data, together with the electrical resistivity on a single crystal under pressure (Phys. Rev. B56, 6627 (1997) ), a Mott-Hubbard phase diagram is proposed for Rb1C60. At ambient pressure this material is suggested to be on the border of the metal-insulator tran sition.