The synthesis of oligo(p-phenylene vinylene) with mesogenic side chains is
described, with the objective to explore highly ordered pi -conjugated mate
rials for functional properties. In the case of dimeric and tetrameric (p-p
henylene vinylene) only a melt transition was observed while in the case of
hexameric (p-phenylene vinylene) a liquid crystalline phase was found unde
r the polarization microscope.