D. Gin et K. Yonezawa, Probing matrix isolation effects in lyotropic liquid crystal nanocomposites using water-soluble PPV, SYNTH METAL, 121(1-3), 2001, pp. 1291-1294
The incorporation of water-soluble poly(sodium phenylenevinylenedicarboxyla
te) in the ordered nanochannels of a hexagonal lyotropic liquid crystal net
work is described. The absorption and emission behavior of the pristine, pr
e-formed PPV derivative in solution, in the bulk solid state, and in the na
nocomposite are compared. The effect of matrix isolation in the nanostructu
red assembly on the conjugation length, conformation, stability, and alignm
ent of the encapsulated PPV chains will be discussed.