Charge mobility in N-picrylarylamine doped polycarbonate

Hole and electron drift mobilities in N-picrylarylamine doped polycarbonate films have been studied by conventional time-of-flight techniques. The cha rge transport molecules contain both electron acceptor and donor functional ities. Electron mobility has a similar value for all the systems since the transport molecules exhibit very close electron affinity. Hole mobility dep ends on the donor functionality. The results can be fit well into a correla ted disorder model when energetic features of the transport molecules are a lso taken into account. For quantum-chemistry calculations, the semi-empiri cal MNDO/PM3 and ZINDO/S methods were used.