A novel method for film formation of polyperinaphthalene (PPN), one of the
low dimensional conducting polymers, is proposed. It is found that excimer
laser ablation (ELA) of mixture targets of PTCDA with Co particles (PTCDA/C
o) with 308nm (XeCl) at a fluence more than 0.8Jcm(-2)pulse(-1) leads to pr
oduce effectively fragments without anhydride groups of PTCDA. FT-IR and Ra
man spectroscopy reveals that ELA of PTCDA/Co enables us to obtain better-d
efined PPN films with electric conductivity of similar to 1x10(-2)Scm(-1) o
n a substrate at 300 degreesC.