Photoinduced energy and electron transfer in a fullerene-sexithiophene-full
erene (C-60-6T-C-60) triad in solvents of different polarity is studied usi
ng photoinduced absorption (PIA) and photoluminescence (PL) spectroscopy. T
he polarity of the solvent has an essential role in the formation and stabi
lization of a photoinduced charge-separated state. Intramolecular electron
transfer is shown to occur in a two-step process, involving singlet-energy
transfer prior to charge separation.