Synthesis of new 1,3,5-tris-styryl-benzene compounds with tunable photo- and electroluminescent properties

Citation
B. Behnisch et M. Hanack, Synthesis of new 1,3,5-tris-styryl-benzene compounds with tunable photo- and electroluminescent properties, SYNTH METAL, 121(1-3), 2001, pp. 1661-1662
Citations number
18
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
121
Issue
1-3
Year of publication
2001
Pages
1661 - 1662
Database
ISI
SICI code
0379-6779(20010315)121:1-3<1661:SON1CW>2.0.ZU;2-M
Abstract
A new series of 1,3,5-tris-styryl-benzene compounds is obtained by Knoevena gel reaction of a 1,3,5-tris-cyanomethylene benzene derivative with three m olecules of a substituted benzaldehyde. The synthesis starting from mesityl ene, followed by bromomethylation or NBS-bromination, bromo-cyano exchange and a threefold condensation reaction leads to a conjugated system with dif ferent optical properties, depending on the substituent in the p-position ( alkyl, alkoxy, amino). The photo- and electroluminescent properties are inv estigated.