Mr. Andersson et al., The effect of the polymerisation temperature on molecular weight and photoluminescence quantum yield for a phenylsubstituted PPV, SYNTH METAL, 119(1-3), 2001, pp. 63-64
We present the synthesis and characterisation of poly(2-(2',5'-bis(2''-ethy
lhexyloxy)phenyl)-1,4-phenylenevinylene) (BEHP-PPV) polymerised under diffe
rent conditions. The photoluminescence efficiencies (eta (PL)) in the solid
state of BEHP-PPV obtained at 144 degreesC and 0 degreesC are 28% and 60%,
respectively. Polymerisation temperatures below 0 degreesC decreases the m
olecular weight without changing the photoluminescence efficiency to any la
rge extent.