Characterisation of poly(3,4-ethylenedioxythiophene) films polymerised in aqueous media

Citation
Hj. Ahonen et al., Characterisation of poly(3,4-ethylenedioxythiophene) films polymerised in aqueous media, SYNTH METAL, 119(1-3), 2001, pp. 119-120
Citations number
6
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
119
Issue
1-3
Year of publication
2001
Pages
119 - 120
Database
ISI
SICI code
0379-6779(20010315)119:1-3<119:COPFPI>2.0.ZU;2-S
Abstract
Highly conducting poly(3,4-ethylenedioxythiophene) films have been electros ynthesised in aqueous medium. The highest in situ conductivity of the films obtained in pure aqueous medium was of the same order than with the films polymerised in organic solvents. The UV-Vis characterisation of the films s howed that the average conjugation length of the polymer chains was affecte d only slightly by selecting water as the electrosynthesis medium. Furtherm ore, FTIR measurements indicated that no ring opening or overoxidation of t he films had occurred in either media.