Cfo. Graeff et Ca. Brunello, Aging effects in polyaniline studied by electrically detected magnetic resonance, SYNTH METAL, 119(1-3), 2001, pp. 327-328
The effects of thermal treatments in inert atmosphere on polyaniline films
have been investigated by electrically detected magnetic resonance (EDMR) a
nd Electron Spin Resonance (ESR). Two lines are observed both by ESR a narr
ow resonance line with a linewidth of approx. 0.24 mT and a broader line wi
th 1.6 mT linewidth, with similar g-factors (2.003), for EDMR with sandwich
contacts only the broader line is observed. The broad EDMR signal is not s
ensitive to the presence of oxygen or moisture, as is the case of electron
spin resonance and conductivity.