Interactions between polyanilines and palladium ions: similarities and differences

Authors
Hasik, M Drelinkiewicz, A Wenda, E
Citation
M. Hasik et al., Interactions between polyanilines and palladium ions: similarities and differences, SYNTH METAL, 119(1-3), 2001, pp. 335-336
Citations number
5
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
119
Issue
1-3
Year of publication
2001
Pages
335 - 336
Database
ISI
SICI code
0379-6779(20010315)119:1-3<335:IBPAPI>2.0.ZU;2-Z
Abstract
llPolyaniline (PANI), poly(o-toluidine) (POT) and poly(o-chloroaniline) (PO C) were treated with PdCl2, palladium (II) acetate and palladium (II) acety lacetonate in organic solvents. It was found that polymer-palladium interac tions involved predominantly a redox-type reaction which resulted in the pa rtial oxidation of the polymer chain with simultaneous reduction of some Pd 2(+) to Pd-0. In the systems studied PANI exhibited the strongest redox pro perties towards Pd2+ ions, POT weaker and POC the weakest ones.