Influence of bipolaron lattice formation on CV, ESR and EQCM at finite rate constants

Authors
Nguyen, PH Paasch, G
Citation
Ph. Nguyen et G. Paasch, Influence of bipolaron lattice formation on CV, ESR and EQCM at finite rate constants, SYNTH METAL, 119(1-3), 2001, pp. 341-342
Citations number
7
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
119
Issue
1-3
Year of publication
2001
Pages
341 - 342
Database
ISI
SICI code
0379-6779(20010315)119:1-3<341:IOBLFO>2.0.ZU;2-7
Abstract
Bipolaron lattice formation increases polaron and bipolaron formation energ ies leading to modified formal potentials to be used in the Nernst equation s. In this manner one describes the capacitive CV current plateau above the redox potential and the asymmetric ESR intensity with a tail. The inclusio n of finite rate constants gives in addition the peak separation and the qu alitative dependence of electrochemical quartz crystal microbalance results .