Hydrogen-induced properties of copper coordination polymer: catena-mu-N,N '-bis-(hydroxyethyl) dithiooxamidatocopper(II)

Authors
Fujishima, M Kanda, S Mitani, T Kitagawa, H
Citation
M. Fujishima et al., Hydrogen-induced properties of copper coordination polymer: catena-mu-N,N '-bis-(hydroxyethyl) dithiooxamidatocopper(II), SYNTH METAL, 119(1-3), 2001, pp. 485-486
Citations number
11
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
119
Issue
1-3
Year of publication
2001
Pages
485 - 486
Database
ISI
SICI code
0379-6779(20010315)119:1-3<485:HPOCCP>2.0.ZU;2-2
Abstract
The hydrogen doping was electrochemically performed on the title coordinati on polymer, catena-mu -N,N'-bis-(hydroxyethyl) dithiooxamidatocopper(II), a nd the hydrogen-induced structural and physical properties were investigate d. From powder X-ray diffraction (XRD) measurement the main framework of tw o-dimensional coordination polymer was found to be unchanged during hydroge n doping. From IR measurement doped hydrogen atoms were revealed to bond to nitrogen atoms of the ligands.