Optical and electronic properties of thin PDAs films with very narrow excitonic bandwidth

Citation
R. Piccardo et al., Optical and electronic properties of thin PDAs films with very narrow excitonic bandwidth, SYNTH METAL, 119(1-3), 2001, pp. 565-566
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
119
Issue
1-3
Year of publication
2001
Pages
565 - 566
Database
ISI
SICI code
0379-6779(20010315)119:1-3<565:OAEPOT>2.0.ZU;2-T
Abstract
Soluble polycarbazolyldiacetylene systems (PCDAs) having long alkyl chains on the carbazolyl substituents have been recently prepared. In these system s, PCDAs chains in the solid state are assembled in hexagonal columnar stru ctures. Thin films of these PCDAs show a very high value for the third orde r susceptibility. In order to study the effect of the substituents in the e lectronic properties of PCDAs we have inserted -CO(CH2)(n)CH3 groups on the carbazolyl rings, thus decreasing the electron-donor effect of carbazole. Non-birefringent thin films of excellent optical quality are obtained whose optical and electronic properties are here reported.