R. Piccardo et al., Optical and electronic properties of thin PDAs films with very narrow excitonic bandwidth, SYNTH METAL, 119(1-3), 2001, pp. 565-566
Soluble polycarbazolyldiacetylene systems (PCDAs) having long alkyl chains
on the carbazolyl substituents have been recently prepared. In these system
s, PCDAs chains in the solid state are assembled in hexagonal columnar stru
ctures. Thin films of these PCDAs show a very high value for the third orde
r susceptibility. In order to study the effect of the substituents in the e
lectronic properties of PCDAs we have inserted -CO(CH2)(n)CH3 groups on the
carbazolyl rings, thus decreasing the electron-donor effect of carbazole.
Non-birefringent thin films of excellent optical quality are obtained whose
optical and electronic properties are here reported.