The optical properties of a luminescent polymer, poly[1,4-phenylene-1,2-di(
phenoxyphenyl)] vinylene (DPOP-PPV), have been investigated, Measurement of
photoluminescence (PL) quantum efficiency shows an unusual increase in eff
iciency in the solid state over solution, 52% to 6% respectively. Investiga
tions into the stimulated emission properties of this material were carried
out but no amplified spontaneous emission was observed. To investigate the
presence of excited state absorption features photoinduced absorption (PA)
measurements were performed. An extended polaron absorption band, from 1.5
eV to 2.25 eV was observed. This overlaps the emission spectra and therefo
re inhibits stimulated emission. This highlights the need to consider the e
ffects of excited state absorption on the emission when synthesising new ma
terials.