Theoretical absorption spectra of charged oligodiacetylenes

Citation
M. Ottonelii et al., Theoretical absorption spectra of charged oligodiacetylenes, SYNTH METAL, 119(1-3), 2001, pp. 611-612
Citations number
4
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
119
Issue
1-3
Year of publication
2001
Pages
611 - 612
Database
ISI
SICI code
0379-6779(20010315)119:1-3<611:TASOCO>2.0.ZU;2-L
Abstract
We perform quantum chemical calculations on the singly and doubly charged s pecies of the lowest unsubstituted oligodiacetylenes, in order to achieve i nformation on the charged states originated in the photoexcitation of polyd iacetylenes. On the basis of the optimized AMI geometries of the radical io ns and dications we obtain their low-energy vertical transitions in an INDO -SCI framework to ensure a proper treatment of electron correlation effects . We get the simulated absorption spectra of the charged oligomers by a con volution of the transition energies, and compare the linearly extrapolated polymer values with the photoinduced absorption results.