Ma. Loi et al., Pressure-induced quenching of the photoluminescence in sexithiophene single crystals observed by femtosecond spectroscopy, SYNTH METAL, 119(1-3), 2001, pp. 645-646
The influence of interchain interactions on the photoluminescence processes
in a sexithiophene single crystal is studied by applying hydrostatic press
ure up to 60 kbar, Steady state and femtosecond-time resolved optical spect
roscopies indicate that an ultrafast (100 fs) formation of intermolecular s
pecies induced by pressure accounts for the observed strong decrease of the
photoluminescence quantum yield.