VIBRATIONAL SPECTROSCOPY OF HYDROXY-HETEROBIARYLS - LOW-FREQUENCY MODES OF 2-(2-HYDROXYPHENYL)-3-PYRIDYNOL

Authors
BOROWICZ P FAURSKOVNIELSEN O CHRISTENSEN DH ADAMOWICZ L LES A WALUK J
Citation
P. Borowicz et al., VIBRATIONAL SPECTROSCOPY OF HYDROXY-HETEROBIARYLS - LOW-FREQUENCY MODES OF 2-(2-HYDROXYPHENYL)-3-PYRIDYNOL, Journal of molecular structure, 408, 1997, pp. 363-366
Citations number
6
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
408
Year of publication
1997
Pages
363 - 366
Database
ISI
SICI code
0022-2860(1997)408:<363:VSOH-L>2.0.ZU;2-N
Abstract
Influence of intermolecular hydrogen bonding upon the vibrational patt ern in the low-frequency region was studied for 2-(2-hydroxyphenyl)-3- pyridynol-a molecule which reveals both intra and intermolecular hydro gen bonds in the crystal phase. Combined use of IR and Raman spectrosc opy and ab initio 6-31G* calculations for the isolated and water-comp lexed compound made it possible to find low frequency transitions corr esponding to the vibrations of the water solvate. (C) 1997 Elsevier Sc ience B.V.