RAMAN-SPECTROSCOPY OF NONBRIDGED, DINUCLEAR COMPLEXES

Authors
SCHATZLEIN A SCHUBART M FINDEIS B GADE LH FICKERT C PIKL R KIEFER W
Citation
A. Schatzlein et al., RAMAN-SPECTROSCOPY OF NONBRIDGED, DINUCLEAR COMPLEXES, Journal of molecular structure, 408, 1997, pp. 373-377
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular structure → ACNP
ISSN journal
00222860
Volume
408
Year of publication
1997
Pages
373 - 377
Database
ISI
SICI code
0022-2860(1997)408:<373:RONDC>2.0.ZU;2-D
Abstract
Raman spectra of the complexes MeSi[Me2SiN(p-Tol)](3)M-M'Cp(CO)(2) (Me = CH3, p-Tol = para-CH3-C6H4, Cp = eta(5)- C5H5) with M=Ti, M'=Fe (1a ) and M=Ti, M'=Ru (1b) and the dinuclear complex MeSi[Me2SiN(p-Tol)](3 )M-Co(CO)(3)(PR3) with M=Ti, R=p-Tol (2a) and M=Zr, R=C6H5 (2b) as wel l as of the titanium bromide complex MeSi[Me2SiN(p-Tol)](3)Ti-Br (3) h ave been measured. Comparison of the spectra, together with data from literature of the different ligands, allows an assignment of the chara cteristic vibrational bands of the two metal fragments. (C) 1997 Elsev ier Science B.V.