Formation of alkaline earth metal-arsenic cages via the metalation of triisopropylsilylarsane with calcium, strontium, and barium bis[bis(trimethylsilyl)amide] in tetrahydrofuran
M. Westerhausen et al., Formation of alkaline earth metal-arsenic cages via the metalation of triisopropylsilylarsane with calcium, strontium, and barium bis[bis(trimethylsilyl)amide] in tetrahydrofuran, Z ANORG A C, 627(5), 2001, pp. 882-890
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
The metalation of triisopropyisilylarsane with the alkaline earth metal bis
[bis(trimethylsilyl)amides] in tetrahydrofuran yields the THF complexes of
calcium (1), strontium (2), and barium-bis(triisopropylsilylarsanide) (3).
Dissolving of these compounds in toluene leads to the elimination of triiso
propylsilylarsane and the formation of the THF complexes of tetraalkaline e
arth metal hexakis( triisopropylsilylarsanide)-triisopropylsilylarsanediide
of calcium (4), strontium (5), and barium (6), respectively. The central p
olyhedron of compound 4 can be described as two trigonal bipyramids with th
e metal atoms in apical positions, connected via the arsanediide substituen
t as a common corner. The central moieties of the compounds 5 and 6 consist
of four trigonal bipyramids which are connected by common edges as well as
common faces.