The application of nanosecond voltage pulses to electrodes provides three w
ays to conduct local electrochemistry on the micro- to nanometer scale. (1)
The finite charging time of the double-layer capacity allows the machining
of three-dimensional microstructures. (2) In an electrochemical scanning t
unneling microscope, reactions are confined to the tunneling region, due to
the depletion of the electrolyte in the tip-surface gap. (3) Ordering proc
esses, following very fast electrochemical reactions, lead to unconventiona
l island patterns on a surface.