W. Irber et al., EXPERIMENTAL, GEOCHEMICAL, MINERALOGICAL AND O-ISOTOPE CONSTRAINTS ONTHE LATE-MAGMATIC HISTORY OF THE FICHTELGEBIRGE GRANITES (GERMANY), Geologische Rundschau, 86, 1997, pp. 110-124
Mineralogical, experimental, geochemical and stable-isotope data give
evidence for an aqueous late-stage fluid which develops increasingly f
rom the less to the more highly evolved granites of the Fichtelgebirge
(G1-G4). In less-evolved granites (particularly G1) only minor chlori
tization and sericitization, minor hydration and corrosion of zircons,
low leachable fractions of Sr and Zr, the nearly chondritic ratios of
Zr/Hf and Y/Ho, and rare-earth-element (REE) patterns lacking the tet
rad effect provide evidence of a less-differentiated granitic melt sys
tem, poor in complexing agents and water, with insignificant late magm
atic fluid-rock interaction. The subsequent low-temperature alteration
, which is suggested by oxygen-isotope composition of quartz and bioti
te, did not affect the whole-rock chemical composition. In the highly
evolved granites (particularly G4), albitization, sericitization and f
luoritization. ubiquitous hydration and corrosion of zircons, high lea
chable fractions of Sr and Zr, Zr/Hf and Y/Ho ratios very different fr
om the chondritic ratios, and REE patterns showing a marked tetrad eff
ect point to the presence of a highly specialized fluid system, rich i
n water and complexing agents. such as fluorine. leading to a marked m
agmatic-hydrothermal alteration. The oxygen isotopes also indicate alt
eration by high-temperature fluids which were likely exsolved during t
he final stage of crystallization.