We have studied the dynamics of the initial stages of silicon nitride forma
tion on silicon surfaces under nitrogen beam bombardment in the secondary i
on mass spectrometry apparatus. We have shown that the secondary ion signal
exhibits damped oscillations below the critical impact angle for nitride f
ormation. We have described this oscillatory response by a second-order dif
ferential equation and argued that it is initiated by some fluctuations in
film thickness followed by the fluctuations in surface charging. (C) 2001 A
merican Institute of Physics.