LiBF4-mediated C-glycosylation of glycals with allyltrimethylsilane: a facile synthesis of allyl C-glycosylic compounds

Citation
Js. Yadav et al., LiBF4-mediated C-glycosylation of glycals with allyltrimethylsilane: a facile synthesis of allyl C-glycosylic compounds, CARBOHY RES, 332(2), 2001, pp. 221-224
Citations number
16
Categorie Soggetti
Agricultural Chemistry","Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
CARBOHYDRATE RESEARCH
ISSN journal
00086215 → ACNP
Volume
332
Issue
2
Year of publication
2001
Pages
221 - 224
Database
ISI
SICI code
0008-6215(20010518)332:2<221:LCOGWA>2.0.ZU;2-E
Abstract
The treatment of glycals with allyltrimethylsilane in the presence of lithi um tetrafluoroborate in acetonitrile gave the corresponding allyl 2,3-unsat urated C-glycosylic compounds in excellent yields with high anomeric select ivity. (C) 2001 Elsevier Science Ltd. All rights reserved.