Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage

Authors
Kakiuchi, F Igi, K Matsumoto, M Chatani, N Murai, S
Citation
F. Kakiuchi et al., Ruthenium-catalyzed dehydrogenative silylation of aryloxazolines with hydrosilanes via C-H bond cleavage, CHEM LETT, (5), 2001, pp. 422-423
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
5
Year of publication
2001
Pages
422 - 423
Database
ISI
SICI code
0366-7022(20010505):5<422:RDSOAW>2.0.ZU;2-C
Abstract
The reaction of aryloxazolines with trialkylhydrosilanes using Ru-3(CO)(12) or Ru(H)(2)(CO)(PPh3)(3) complex as a catalyst resulted in dehydrogenative silylation to form ortho silylated aryloxazolines in good to excellent yie lds. This reaction can be applied to aryloxazolines having either electron- donating (NMe2, OMe, and CH3) or -withdrawing (CF3 and F) groups.