Synthesis, structure, and photochemistry of 2-silyl- and 2-disilanyl-2-aryl-1,3-dithiane derivatives

Authors
Reddy, AM Tsutsui, S Sakamoto, K
Citation
Am. Reddy et al., Synthesis, structure, and photochemistry of 2-silyl- and 2-disilanyl-2-aryl-1,3-dithiane derivatives, CHEM LETT, (5), 2001, pp. 476-477
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
5
Year of publication
2001
Pages
476 - 477
Database
ISI
SICI code
0366-7022(20010505):5<476:SSAPO2>2.0.ZU;2-1
Abstract
A series of 2-silyl- and 2-disilanyl-substituted 2-aryl-1,3-dithiane deriva tives were prepared by the reactions of 2-aryl-2-lithio-1,3-dithianes with the corresponding chlorosilanes. Photolysis of 2-phenyl-2-(pentamethyldisil anyl)-1,3-di resulted in the intermediary formation of 1,1-dimethyl-2-pheny l-2-(trimethylsilyl)-1-silaethene.