Studies of thin liquid films, made from semidilute polyelectrolyte solution
s, are presented. The disjoining pressure variation with film thickness exh
ibits oscillations, corresponding to film stratification. The oscillations
become sharper as the polymer concentration c increases, and disappear when
salt is added. The period of the oscillations scales as c(-1/2). The obser
ved stratification is related to the polymer network and the size of the st
eps to the mesh size xi.