REACTIONS INVOLVING FLUORIDE-ION .39. REACTIONS OF PERFLUORINATED DIENES WITH OXYGEN AND SULFUR NUCLEOPHILES

Authors
BRISCOE MW CHAMBERS RD MULLINS SJ NAKAMURA T VAUGHAN JFS
Citation
Mw. Briscoe et al., REACTIONS INVOLVING FLUORIDE-ION .39. REACTIONS OF PERFLUORINATED DIENES WITH OXYGEN AND SULFUR NUCLEOPHILES, Journal of the Chemical Society. Perkin transactions. I, (21), 1994, pp. 3119-3124
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
21
Year of publication
1994
Pages
3119 - 3124
Database
ISI
SICI code
0300-922X(1994):21<3119:RIF.RO>2.0.ZU;2-E
Abstract
The order of reactivity of perfluorinated dienes towards methanol is 3 > 2 much greater than 1 and the process is activated by release of an gle strain. The diene 1 is hydrolysed to give perfluorotetramethyl-fur an and the corresponding thiophene, is obtained by an analogous proces s using K2S. Hydrolysis of compounds 2 and 3 yields diketones that are strong acids. Reactions of phenols and thiophenols with 1 give aryl e thers and sulfides and difunctional nucleophiles react with 1 to give potential polymer precursors.