THE PHOSPHORYLATION OF ORGANIC-COMPOUNDS BY PHOSPHORIC ANHYDRIDE .3. SYNTHESIS OF MONOSUBSTITUTED KETENES IN THE REACTION OF ESTERS WITH PHOSPHORIC ANHYDRIDE AND CYCLOTRIMERIZATION OF THESE KETENES

Authors
EFREMOV DA ZAVLIN PM ESSENTSEVA NS TEBBY JC
Citation
Da. Efremov et al., THE PHOSPHORYLATION OF ORGANIC-COMPOUNDS BY PHOSPHORIC ANHYDRIDE .3. SYNTHESIS OF MONOSUBSTITUTED KETENES IN THE REACTION OF ESTERS WITH PHOSPHORIC ANHYDRIDE AND CYCLOTRIMERIZATION OF THESE KETENES, Journal of the Chemical Society. Perkin transactions. I, (21), 1994, pp. 3163-3168
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
21
Year of publication
1994
Pages
3163 - 3168
Database
ISI
SICI code
0300-922X(1994):21<3163:TPOOBP>2.0.ZU;2-M
Abstract
Monosubstituted ketenes 1 have been synthesized from substituted aceti c esters 2 by elimination of alcohol under the action of phosphoric an hydride. The ketenes undergo cyclotrimerization to give substituted ph loroglucinols (1,3,5-trihydroxybenzenes) 3 and their phosphorylated de rivatives.