[{ReH2(PMePh2)(2)}(mu-H)(3)](-): The first member of a new class of anionic polyhydride dimers [Re2H7L4](-)

Authors
Hinman, JG Abdur-Rashid, K Lough, AJ Morris, RH
Citation
Jg. Hinman et al., [{ReH2(PMePh2)(2)}(mu-H)(3)](-): The first member of a new class of anionic polyhydride dimers [Re2H7L4](-), INORG CHEM, 40(11), 2001, pp. 2480
Citations number
21
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
40
Issue
11
Year of publication
2001
Database
ISI
SICI code
0020-1669(20010521)40:11<2480:[TFMOA>2.0.ZU;2-O
Abstract
[K(Q)] [{ReH2(PMePh2)(2)}(2)(mu -H)(3)] is prepared by treatment of {ReH2(P MePh2)(2)}(2)(mu -H)(4) with potassium hydride and a crown ether (Q = 18-cr own-6 or 1,10-diaza-18-crown-6). The [K(1,10 diaza-18-crown-6)](+) salt con tains NH . . . HRe protonic-hydridic bonds and has been characterized by P- 31 NMR, variable temperature H-1 NMR, IR, and X-ray crystallography. The pK (alpha)(THF) = 33 of {ReH2(PMePh2)(2)}(2)(mu -H)(4) was determined on the b asis of its reaction with [K(2,2,2-crypt)][PO(OEt)(2)NPh]. [GRAPHICS]