INTRAMOLECULAR O-H INSERTION REACTION OF AZIDO SUBSTITUTED DIAZOESTERS AND ITS RELEVANCE TO THE MECHANISM OF THE ALLYLIC AZIDE REARRANGEMENT

Authors
PADWA A SA MM
Citation
A. Padwa et Mm. Sa, INTRAMOLECULAR O-H INSERTION REACTION OF AZIDO SUBSTITUTED DIAZOESTERS AND ITS RELEVANCE TO THE MECHANISM OF THE ALLYLIC AZIDE REARRANGEMENT, Tetrahedron letters, 38(29), 1997, pp. 5087-5090
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
29
Year of publication
1997
Pages
5087 - 5090
Database
ISI
SICI code
0040-4039(1997)38:29<5087:IOIROA>2.0.ZU;2-6
Abstract
The Rh-2(OAc)(4) catalyzed decomposition of gamma-azido-delta-hydroxy diazoesters affords 3(2H)-furanones derived by a sequential O-H insert ion followed by a concerted [3,3]-sigmatropic shift of the azido group . (C) 1997 Elsevier Science Ltd.