We present in a simple terms the theory of the factorizing operator introdu
ced recently by Maillet and Sanches de Santos for the spin-1/2 chains. We o
btain the explicit expressions for the matrix elements of the factorizing o
perator in terms of the elements of the monodromy matrix. We use this resul
ts to derive the expression for the general scalar product for the quantum
spin chain. We comment on the previous determination of the scalar product
of Bethe eigenstate with an arbitrary dual state. We also establish the dir
ect correspondence between the calculations of scalar products in the F-bas
is and the usual basis.