MANIPULATION OF THE REDUCTION POTENTIALS OF WURSTERS-BLUE DERIVATIVESVIA STERIC AND CONFORMATIONAL EFFECTS

Authors
PEARSON AJ GELORMINI AM
Citation
Aj. Pearson et Am. Gelormini, MANIPULATION OF THE REDUCTION POTENTIALS OF WURSTERS-BLUE DERIVATIVESVIA STERIC AND CONFORMATIONAL EFFECTS, Tetrahedron letters, 38(29), 1997, pp. 5123-5126
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
29
Year of publication
1997
Pages
5123 - 5126
Database
ISI
SICI code
0040-4039(1997)38:29<5123:MOTRPO>2.0.ZU;2-6
Abstract
Using [eta(6)-cyclopentadienyliron](+)-mediated SNAr chemistry, a seri es of symmetrical and 2-alkyl tetra-alkyl-p-phenylenediamines have bee n prepared. The amine/amine(.+) first redox couple has been determined for each member of the series and is influenced by remote steric, ele ctronic, and conformational effects. (C) 1997 Elsevier Science Ltd.